This is the third time we mention spectroscopy as a means of performing compressive measurements. We first had the CheMin instrument aboard Curiosity then, last week, the case of the Randomized MALDI TOF MS/MS system. What all these systems share is this characteristic feature of the data i.e. spectra that are sparse. It's a clue.
....Fourier transform spectroscopy is a less intuitive way to get the same information. Rather than allowing only one wavelength at a time to pass through to the detector, this technique lets through a beam containing many different wavelengths of light at once, and measures the total beam intensity. Next, the beam is modified to contain a different combination of wavelengths, giving a second data point. This process is repeated many times. Afterwards, a computer takes all this data and works backwards to infer how much light there is at each wavelength....
Oh ok. They already do multiplexing, Check.
To be more specific, between the light source and the detector, there is a certain configuration of mirrors that allows some wavelengths to pass through but blocks others (due to wave interference). The beam is modified for each new data point by moving one of the mirrors; this changes the set of wavelengths that can pass through.
Oh ok, they already perform several multiplexings. Check
As mentioned, computer processing is required to turn the raw data (light intensity for each mirror position) into the desired result (light intensity for each wavelength). The processing required turns out to be a common algorithm called the Fourier transform (hence the name, "Fourier transform spectroscopy"). The raw data is sometimes called an "interferogram". Because of the existing computer equipment requirements, and the ability of light to analyze very small amounts of substance, it is often beneficial to automate many aspects of the sample preparation. The sample can be better preserved and the results are much easier to replicate.
Oh, ok. A computational inversion process (albeit a linear one) is needed to get back the (sparse) data. Check.
Now, more precisely on the topic of Fourier Transform Infra-Red Spectroscopy, we can read more on the advantages of such techniques
There are two principal advantages for an FT spectrometer compared to a scanning (dispersive) spectrometer.
- The multiplex or Fellgett's advantage. This arises from the fact that information from all wavelengths is collected simultaneously. It results in a higher Signal-to-noise ratio for a given scan-time or a shorter scan-time for a given resolution.
- The throughput or Jacquinot's advantage. This results from the fact that, in a dispersive instrument, the monochromator has entrance and exit slits which restrict the amount of light that passes through it. The interferometer throughput is determined only by the diameter of the collimated beam coming from the source.Other minor advantages include less sensitivity to stray light, and "Connes' advantage" (better wavelength accuracy), while a disadvantage is that FTIR cannot use the advanced electronic filtering techniques that often makes its signal-to-noise ratio inferior to that of dispersive measurements.
They are all elements we know are exactly why compressive sensing systems are interesting. Here is an interesting historical tidbit:
By making measurements of the signal at many discrete positions of the moving mirror, the spectrum can be reconstructed using a Fourier transform of the temporal coherence of the light. Michelson spectrographs are capable of very high spectral resolution observations of very bright sources. The Michelson or Fourier transform spectrograph was popular for infra-red applications at a time when infra-red astronomy only had single pixel detectors.
How do we turn these FTIRS systems into compressive one ? well for one, quite simply by using one of these solvers instead of an Inverse Fourier Transform when "inverting" the spectrogram back to the actual (sparse) spectra. By using these solvers, you are in effect:
- expecting the spectra to be sparse.
- and potentially reducing the number of measurements (ideally, the number of measurement could be equal to the number of peaks, see last week's entry)
P.S.: I'll just add this Compressive Fourier Transform Infra-Red Spectrometer technique to the list of technologies that do not exist.
P.S. 2: At some point in time, I was involved in some tiny aspect of the payload bus of the now canceled Geostationary Infrared Fourier Transform Spectroscopy (GIFTS) satellite..
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